Ethyl Butyrate – Food Grade/Fragrance Grade

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Chemical Identity

  • Chemical Name: Ethyl Butyrate (Ethyl Butanoate)
  • CAS Number: 105-54-4
  • Chemical Formula: C₆H₁₂O₂
  • Molecular Weight: 116.16 g/mol
  • Structure: CH₃-CH₂-CH₂-COO-CH₂-CH₃ (an ester of ethanol and butyric acid)

Physical Properties

  • Appearance: Clear, colorless liquid
  • Odor: Sweet, fruity, resembling pineapple or tropical fruits
  • Boiling Point: ~120°C (~248°F)
  • Melting Point: -93°C (-135°F)
  • Flash Point: ~22°C (~72°F), Closed Cup
  • Density: 0.879 g/cm³ at 20°C
  • Refractive Index: 1.393 at 20°C
  • Solubility in Water: Slightly soluble (~1.7 g/L at 20°C)
  • Miscibility: Miscible with alcohols, ethers, and most organic solvents

Chemical Properties

  • Purity: ≥ 99% (typical for commercial or industrial grade)
  • Functional Group: Ester
  • Vapor Pressure: 6.1 kPa at 20°C
  • Auto-ignition Temperature: ~450°C (~842°F)
  • Partition Coefficient (log P): ~1.85 (octanol/water)

Description

Ethyl butyrate (also known as Ethyl butanoate) is a simple, naturally occurring ester with a sweet, fruity aroma. It is widely used across several industries, including food and beverages, fragrances, and industrial manufacturing.

Applications of Ethyl Butyrate

Food and Beverage Industry

  • Soft Drinks: Enhances citrus-based flavors like orange, pineapple, and mango.
  • Candies: Adds a sweet and fruity flavor to hard and soft candies.
  • Baked Goods: Used in cakes, pastries, and cookies for its fruity essence.
  • Ice Creams and Desserts: Enhances the flavor profile of tropical-themed products.
  • Alcoholic Beverages: Provides a fruity note to cocktails, liqueurs, and craft beers.

Fragrance Industry

  • Perfumes and Colognes: Used in floral, fruity, and tropical-themed scents.
  • Personal Care Products: Found in shampoos, lotions, and body washes for a refreshing aroma.
  • Air Fresheners: Commonly used in home and car fresheners for a clean, fruity scent.

Industrial Applications

  • Solvent: Used in coatings, adhesives, and paints due to its ability to dissolve organic compounds effectively.
  • Plasticizer: Incorporated in plastics to improve flexibility and durability.
  • Resins and Polymers: Aids in the formulation of certain synthetic materials.

Natural Product Enhancement

  • Fruit Ripening and Preservation: Used to mimic natural fruit aromas in artificial ripening processes.
  • Artificial Flavors: Enhances the natural taste of processed fruits, particularly in jams and canned goods.

Pharmaceutical Industry

  • Used as a flavor masking agent in medicines and supplements to improve palatability, especially in chewables and syrups.
  • Employed as an excipent in formulations for drug delivery systems.

Agriculture

  • Used in insect attractants for monitoring and controlling pest populations.
  • Applied in the formulation of biopesticides.

Cosmetics

  • Incorporated in lip balms, flavored glosses, and beauty products for its sweet and appealing aroma.

Research and Development

  • Extensively used in chemical research for studying esterification reactions and solvent applications.

Storage Guidelines

  • Temperature:
    • Store in a cool, dry place, ideally between 15°C and 25°C (59°F to 77°F). Avoid exposure to high temperatures or direct sunlight.
  • Container:
    • Keep in tightly sealed, corrosion-resistant containers (such as HDPE, stainless steel, or glass) to prevent leaks and contamination.
    • Ensure containers are labeled correctly to avoid misuse.
  • Ventilation:
    • Store in a well-ventilated area to minimize the accumulation of vapors, which can be flammable.
  • Segregation:
    • Keep away from incompatible substances like strong acids, bases, oxidizing agents, and sources of ignition (e.g., flames, sparks, static electricity).
  • Spill Containment:
    • Use secondary containment (such as a spill tray) to manage accidental leaks or spills.

Handling Guidelines

  • Personal Protective Equipment (PPE):
    • Wear appropriate PPE, including:
      • Chemical-resistant gloves (e.g., nitrile or neoprene)
      • Safety goggles or face shield
      • Long-sleeved lab coat or protective clothing
      • Respiratory protection if handling in poorly ventilated areas
  • Work Area:
    • Handle in a fume hood or a well-ventilated space to prevent vapor accumulation.
    • Avoid inhalation, skin contact, and eye contact.
  • Preventive Measures:
    • Ground and bond containers when transferring Ethyl butyrate to prevent static discharge.
    • Use tools and equipment rated for use with flammable substances.
  • First Aid Measures:
    • Inhalation: Move to fresh air immediately. Seek medical attention if symptoms persist.
    • Skin Contact: Wash thoroughly with soap and water. Remove contaminated clothing.
    • Eye Contact: Rinse eyes cautiously with water for several minutes. Seek medical help if irritation persists.
    • Ingestion: Do not induce vomiting. Rinse mouth with water and seek medical attention.

Additional information

Size

100mL (3.3 Fl Oz), 250mL (8 Fl Oz), 500mL (16 Fl Oz), 1000mL (32 Fl Oz)